The imine-exchange strategy makes single-crystal growth of covalent organic frameworks (COFs) with large size (>15 microns) possible but is a time-consuming process (15 to 80 days) that has had limited success (six ex...

https://www.science.org/doi/epdf/10.1126/science.adk8680

Growth of covalent organic frameworks (COFs) as single crystals is extremely challenging. Inaccessibility of open-structured single-crystal COFs prevents the exploration of structure-oriented applications. Herein we r...

https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202007230

This review systematically summarizes the development and application of various synthetic strategies for covalent crystals, including the modulator approach, seed-mediated growth, interfacial synthesis, and supercrit...

https://download.sciengine.com/cfs/files/pdfs/view/0023-074X/FEDF46E96A8C4820AFF99E09D9AFF7E3.pdf